Concept:In an ionic compound, the total positive charge must balance the total negative charge.
Explanation:Aluminium has atomic number 13 and electronic configuration
2,8,3.
It can lose 3 electrons to become stable, so its valency is 3, written as
Al3+.
Sulphur has atomic number 16 and electronic configuration
2,8,6.
It needs to gain 2 electrons to complete its octet, so its valency is 2, written as
S2−.
In the formula
AlyS3, the subscript 3 on sulphur means there are 3 sulphide ions.
The total negative charge is therefore
3×(−2)=−6.
Each aluminium ion carries a charge of
+3.
To balance the compound, the total positive charge must be
+6.
So,
y×(+3)=+6, which gives
y=2.
Hence, the correct formula is
Al2S3.
Answer:The value of
y is 2, which is option B.