Concept:In a stable compound the total combining power (valency) of one element equals that of the other. The criss-cross method swaps the valencies and writes them as subscripts.Solution:Valency of sodium =1, valency of oxygen =2.Cross the valencies: the 2 of oxygen becomes the subscript of Na, and the 1 of sodium becomes the subscript of O:Na2O1=Na2O (a subscript 1 is not written).Check: 2 sodium atoms give 2×1=2 units of combining power, which equals the 2 of one oxygen atom.
Key point:NaO leaves oxygen with one unused combining power, and Na2O2 (sodium peroxide) does not follow the simple valencies 1 and 2.Answer:Option B (Na2O)