Concept:Number of atoms is found by converting the given mass to moles, then using Avogadro's constant.Explanation:Molar mass of SO2=32.0+2(16.0)=64.0g mol−1Moles of SO2 in 3.20 g:Moles of SO2=64.03.20=0.050 molEach SO2 molecule contains exactly one sulphur atom.So, moles of sulphur atoms =0.050 molNumber of sulphur atoms =0.050×6.02×1023=3.01×1022 atomsAnswer:A. 3.01×1022