Concept:A species has no electron in the 3d-orbital when its electronic configuration shows that all 3d orbitals are empty.Explanation:Write the outer electronic configurations and remove electrons according to the charge.Scandium has 1s22s22p63s23p63d14s2.For Sc3+, remove three electrons: first from 4s, then from 3d.So, Sc3+ becomes 1s22s22p63s23p6.Thus, Sc3+ has completely empty 3d-orbitals.Answer:Sc3+ — Option B.