Concept:The valence electron is the electron in the outermost shell, and its orbital type can be found from the electron configuration.Explanation:Sodium has atomic number 11, so it has 11 electrons.Its electron configuration is 1s22s22p63s1.The outermost shell is the third shell, and the valence electron is in the 3s orbital.The 3s orbital is an s-orbital, so sodium has its valence electron in the s-orbital.Aluminum, phosphorus, and carbon have valence electrons in p-orbitals as well.Answer:C. Sodium