Concept:A precipitate forms when two soluble salts react to produce an insoluble salt.Explanation:Mixing K2SO4 and BaCl2 produces BaSO4, which is insoluble in water.The balanced equation is:BaCl2(aq)+K2SO4(aq)→BaSO4(s)+2KCl(aq)Here, BaSO4 appears as a white precipitate.The other mixtures contain only soluble salts, so no precipitate forms.Answer:C. K2SO4 and BaCl2